دنیای نانو

دنیای نانو

نانوکاتالیزگر ‏‎ Fe3O4@C-ONaدرسنتز مشتقات کومارین-3-کربوکسیلیک اسید: یک رویکرد ‏سازگار با محیط زیست

نوع مقاله : مقاله پژوهشی

نویسندگان
1 گروه شیمی ، واحد کرج، دانشگاه آزاد اسلامی، کرج، ایران
2 گروه شیمی ، واحد میاندوآب، دانشگاه آزاد اسلامی، میاندوآب، ایران
3 گروه شیمی ، دانشگاه پیام نور، تهران، ایران
چکیده
ابتدا نانوذرات مغناطیسی ‏‎(Fe3O4@C-ONa)‎‏ سنتز و توسط طیف‌سنجی مادون‎ ‎قرمز‎ ‎تبدیل فوریه ‏‎(FT-IR)‎، طیف‌سنجی پراش ‏پرتو ایکس ‏‎(XRD)‎، میکروسکوپ الکترونی روبشی ‏‎(SEM)‎‏ و مغناطیس‎‌‎سنج نمونه لرزان ‏‎(VSM)‎‏ شناسایی شدند. این نانوذرات ‏توانستند تراکم نووناگل بین ملدروم اسید و مشتقات سالسیل آلدهید را جهت سنتز مشتقات کومارین-3-کربوکسیلیک اسید با نتایج ‏مطلوب در محیط آبی کاتالیزکنند. انجام واکنش در شرایط حرارتی در حضور 20 درصد وزنی کاتالیزگر مغناطیسی ‏Fe3O4@C-‎ONa‏ در دمای ‏‎°C‎‏80 و حلال آب مناسب ترین نتیجه، در حالی‌که با کمک امواج فراصوت در دمای پایینتر ‏‎°C‎‏ 40 نتایج مطلوب ‏مشاهده شد. نانوذرات مغناطیسی پس از اتمام واکنش به‌ آسانی توسط یک آهنربای خارجی از مخلوط واکنش جدا شد و پس از ‏شستشو جهت استفاده مجدد آماده گردید‎.‎‏ این کاتالیزگر تا شش مرتبه با فعالیت کاتالیزگری مطلوب مورد استفاده قرار ‌گرفت. این ‏پروتکل، روشی جدید، کارآمد، ارزان، در دسترس و دوست‌دار محیط زیست است که مزایای قابل‌توجهی از‌جمله بازده بالای ‏محصولات، زمان کوتاه واکنش، و سهولت تهیه کاتالیزگر و قابلیت جداسازی ساده آن از محصول را نشان داد. ‏
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Fe3O4@C-ONa nanocatalyst for the synthesis of coumarin-3-carboxylic acid derivatives: an ‎environmentally friendly approach

نویسندگان English

Arezoo beirangi 1
Somayeh Soleimani Amiri 1
Behrooz Mirza 1
Farnaz Behmagham 2
Sheida Ahmadi 3
1 Department of Chemistry, Karaj branch, Islamic Azad University, Karaj, Iran
2 Department of Chemistry, Miandoab Branch, Islamic Azad University, Miandoab, Iran
3 Department of Chemistry,, Payame Noor University, Tehran, Iran
چکیده English

First, magnetic nanoparticles (Fe3O4@C-ONa) were synthesized and analyzed by Fourier ‎transform infrared spectroscopy (FT-IR), X-ray diffraction spectroscopy (XRD), scanning ‎electron microscope (SEM) and vibrating sample magnetometer (VSM). These nanoparticles ‎were able to catalyze the Knoevenagel condensation ‎ between Meldrum's acid and ‎salicylaldehyde derivatives for the synthesis of coumarin-3-carboxylic acid derivatives with ‎favorable results in aqueous medium. The most suitable result is to conduct the reaction ‎under thermal conditions in the presence of Fe3O4@C-ONa (20 w%) at a temperature of ‎‎80°C and water as a solvent. In contrast, favorable results were observed in ultrasound-‎assisted conditions at a lower temperature of 40°C. After the completion of the reaction, the ‎magnetic nanoparticles were easily separated from the reaction mixture by an external ‎magnet, and after washing, they were prepared for reuse. This catalyst was used up to six ‎times with desirable catalytic activity. This protocol is a new, efficient, economical, ‎accessible, and environmentally friendly method that indicated significant advantages, ‎including a high yield of products, short reaction time, ease of preparation of the catalyst, ‎and its simple separation from the product. ‎

کلیدواژه‌ها English

Magnetic nanoparticles
Nanocatalyst
Green synthesis
Coumarin-3-carboxylic acid
‎Meldrum's acid
Knoevenagel reaction
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دوره 20، شماره 77
زمستان 1403
صفحه 59-47

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