[1] Chen W, Liu H, Yan Q, Chen Q, Hong M, Zhou Z-X, Fu H. Straightforward synthesis of novel chitosan bio-based flame retardants and their application to epoxy resin flame retardancy. Compos. Commun. 2024;48:101949. DOI: 10.1016/j.coco.2024.101949 .
[2] Ma D, Liao X, Li X, Liu Y, Zhang X. Preparation and characterization of chitosan film modified with polydimethylsiloxane capped by mono-terminal epoxy groups. Int. J. Biol. Macromol. 2025;298:139912. DOI: 10.1016/j.ijbiomac.2024.139912.
[3] Tang X, Ji X, Zhang R, Xu N, Feng Y, Pan L. Preparation and properties of a green material: a seawater degradable polyglycolic acid (PGA)/chitosan (CS) antibacterial composite material. Int. J. Biol. Macromol. 2025;318(Part 2):144993. DOI: 10.1016/j.ijbiomac.2025.144993.
[4] Esmailzadeh M, Tammari E, Safarpour T, Razavian SM, Pezzato L. Anti-corrosion effect of chitin and chitosan nanoparticles in epoxy coatings. Mater. Chem. Phys. 2024;317:129097. DOI: 10.1016/j.matchemphys.2024.129097.
[5] Sarmin SN, Jawaid M, Zaki SA, Radzi AM, Fouad H, Khiari R, Rahayu S, Mohamad Amini MH. Enhancing the properties of date palm fibre reinforced bio-epoxy composites with chitosan – Synthesis, mechanical properties, and dimensional stability. J. King Saud Univ. Sci. 2023;35(7):102833. DOI: 10.1016/j.jksus.2023.102833.
[6] Gunasekaran E, Govindarajan S. Enhanced adhesion and ductility in steel bonding with thermally activated blocked-polyisocyanate derived from chitosan as reinforced cross-linker epoxy resin. Prog. Org. Coat. 2025;200:109008. DOI: 10.1016/j.porgcoat.2025.109008.
[7] Hu G, Khan H, Ali F. Crab shell chitosan infusion: optimizing epoxy-polyamide composites membrane for improved mechanical and thermal properties. Colloid Polym. Sci. 2025;303:277–286. DOI: 10.1007/s00396-024-05347-7 .
[8] Amasee YM, Salih SM. Thermal and Mechanical properties investigations of Epoxy-biobased matrix reinforced with SiC nanoparticles. IOP Conf. Ser.: Earth Environ. Sci. 2025;1507:012084. DOI: 10.1088/1755-1315/1507/1/012084.
[9] Haihua Y, Xiuhang X, Yunfei X, Mingzhen P, Nighat Z, Bo P, Ur Rahman A, Min W, Henmei N. Synthesis of a novel modified chitosan as an intumescent flame retardant for epoxy resin. e-Polymers. 2020;20(1):303–316. DOI: 10.1515/epoly-2020-0031 .
[10] Chen R, Luo Z, Yu X, Tang H, Zhou Y, Zhou H. Synthesis of chitosan-based epoxy composites modified with chitosan derivatives. Int. J. Biol. Macromol. 2024;260(Part 2):129580. DOI:10.1016/j.ijbiomac.2024.129580 .
[11] Shetranjiwalla S, Fasulo A, Rhoden S. Eco-design and tunable structure-properties of chitosan-epoxy-glycerol-silicate biohybrids using integrated crosslinking. Carbohydr. Polym. 2023;299:120187. doi: 10.1016/j.carbpol.2022.120187 .
[12] Xu N, Qiu G-F, Jin L-P, et al. Preparation and properties of fire-retardant epoxy resin containing an environmentally friendly bio-based CS@SA@ZIF-67 core-shell nano-hybrid. Chin. J. Polym. Sci. 2025;43:828–836. doi: 10.1007/s10118-024-3364-5 .
[13] Gunasekaran E, Sumalatha V, Govindarajan S. Thermally switchable chitosan-polycarbamate cross-linked epoxy resin composites with enhanced mechanical strength and UV-A shielding. Ind. Eng. Chem. Res. 2025;64(16):8211–8825. DOI:10.1021/acs.iecr.5c00039.
[14] Sajadifar M, Ehsani M, Zaarei D, Khonakdar HA. Epoxy resin/POSS/chitosan-modified silica nanocomposite: Characterization of thermal and mechanical properties. Polym. Eng. Sci. 2025;65(1):135–148. DOI: 10.1002/pen.26997.
[15] Yang L, Liu C, Zhang D, Yang Z, Wei Z, Fan H, Huang X, Zhao S, He C. Chitosan-functionalized graphitic carbon nitride for enhanced corrosion resistance in epoxy coatings. Colloids Surf. A Physicochem. Eng. Asp. 2025;707:135924. DOI: 10.1016/j.colsurfa.2024.135924.
[16] Guo S, Wu K, Pan Z, Zhou H, Zhou C. Flame retardant, high mechanical strength, transparent and water-resistant flame retardant and its fire resistance in epoxy resin. Carbohydr. Polym. 2020;245:116530. DOI:10.1016/j.carbpol.2020.116530 .
[17] Wu Q, Xiao B, Li Y, Yao R, Jin D, Lei Y, Yang D, Zhu J. Bioactive chitosan/polydopamine nanospheres coating on carbon fiber towards strengthening epoxy composites. Int. J. Biol. Macromol. 2024;275(Part 1):133568. DOI: 10.1016/j.ijbiomac.2023.133568 .
[18] Zhang L, Feng T, Chen H, Dong W, Xu Y, Shen J, Wang X. A multifunctional partially bio-based epoxy resin by renewable chitosan as reaction raw material: Shape memory effect, bonding property, excellent degradability, and toughening performance. Polymer. 2024;315:127851. DOI:10.1016/j.polymer.2024.127851.
[19] Li G, Li Y, Lin C, Peng H, Xue Y, Qin W, Zhao X, Zhou B. Corrosion protective properties on 2024-T3 of chitosan-modified montmorillonite epoxy coatings based on Ce³⁺ loading. J. Appl. Polym. Sci. 2024;141(41):e56080. DOI:10.1002/app.56080.
[20] Surianarayanan P, Balaji N, Balasubramanian K. Mechanical, drop load impact and fatigue properties of silane-treated chitosan and waste leather and areca fibre epoxy composite. Silicon. 2024;16:1015–1024. DOI: 10.1007/s12633-023-02715-w.
[21] Liang M, Liu X, Liu D, Li X, Li T-T, Lin J-H, Chang B, Chen J. Construction of epoxy composites with double alternating “rigid-flexible” structures: Curing kinetics and thermal/mechanical properties. Chem. Eng. J. 2024;502:157547. DOI: 10.1016/j.cej.2024.157547.
[22] El-Shamy OAA, Deyab MA. Novel anticorrosive coatings based on nanocomposites of epoxy, chitosan, and silver. Mater. Lett. 2023;330:133298. DOI: 10.1016/j.matlet.2022.133298 .
[23] Sharif M, Tavakoli S. Biodegradable chitosan-graphene oxide as an effective green filler for improving properties in epoxy nanocomposites. Int. J. Biol. Macromol. 2023;233:123550. doi: 10.1016/j.ijbiomac.2023.123550.
[24] Nepomuceno NC, Fook MVL, Ries A, et al. Bio-based epoxy resins of epoxidized soybean oil cured with salicylic acid loaded with chitosan: Evaluation of physical-chemical properties. J. Polym. Environ. 2023;31:2566–2575. DOI: 10.1007/s10924-022-02585-8.
[25] Ji X, Ji W, Pourhashem S, et al. (TiO₂ /Ag nanoparticles)@(chitosan-polyvinyl alcohol) core-shell nanofibers as novel anticorrosion and antibacterial improvers for epoxy coating systems. J. Polym. Res. 2023;30:244. DOI: 10.1007/s10965-023-03569-x.
[26] Kumar AM, Jose J, Hussein MA. Novel polyaniline/chitosan/reduced graphene oxide ternary nanocomposites: Feasible reinforcement in epoxy coatings on mild steel for corrosion protection. Prog. Org. Coat. 2022;163:106678. DOI: 10.1016/j.porgcoat.2021.106678.
[27] Shadmand M, Alizadeh F, Razavi Aghjeh MK. Chitosan-enhanced vitrimerization of thermoset epoxy resins: Multiple-dynamic networks for sustainable approaches, improved mechanical properties, and rapid stress relaxation. ACS Appl. Polym. Mater. 2025;7(2):1103–1117. DOI: 10.1021/acsapm.4c03738.
[28] Song Z, Zhou J, Jin L, et al. Influence of a novel biobased coating decorated with UiO-66/BN in persistent flame-retardant hybrids on the fire safety and thermal degradation of epoxy resin. Front. Chem. Sci. Eng. 2025;19:43. DOI: 10.1007/s11705-025-2545-2.
[29] O Z, Wang Y, Zhang K, Xia A, Li Q, Yang L, Yu M, Wang D. Synthesis of a fully bio-based tannic acid/chitosan/ferric ions double cross-linked coating: A green and sustainable strategy to enhance the carbon fiber/epoxy composites. ACS Sustain. Chem. Eng. 2025;13(17):6367–6378. DOI: 10.1021/acssuschemeng.5c01406.
[30] Shaisundaram VS, Sengottaiyan S, Mohan R, Gurunathan V. Assessment of mechanical, thermal, and sliding wear performance of chemically treated alumina-filled biocomposites using machine learning and response surface methodology. Polym. Compos. 2025;advance online publication. DOI: 10.1002/pc.29798
[31] Sengottaiyan S, Subbarayan S, Natarajan R, Gurunathan V. Enhancing mechanical, degradation, and tribological properties of biocomposites via treatment and alumina content. J. Reinf. Plast. Compos. 2025;advance online publication. DOI: 10.1177/0731684425132166.
[32] Saravanakumar S, Sathiyamurthy S, Vinoth V, Others. Effect of alumina on epoxy composites with banana fiber: Mechanical, water resistance and degradation property analysis. Fibers Polym. 2024;25:275–287. DOI: 10.1007/s12221-023-00405-3.
[33] Ghaderi H, Semnani A, Moini Jazani O. A new platform for designing high-performance epoxy film adhesive with poly(butyl acrylate-block-styrene) block copolymer and alumina nanoparticles in aluminum-aluminum bonded joints: Preparation and analysis of the mechanical, adhesion, and thermal properties. Polym. Compos. 2024;45(8):7689–7700. DOI: 10.1002/pc.28297.
[34] Sari NH, Suteja S, Pruncu CI, Setyawan I, Ilyas RA, Lamberti L. Physicomechanical, water absorption and thermal properties and morphology of Paederia foetida fiber–Al₂ O₃ powder hybrid-reinforced epoxy composites. Polym. Int. 2024;73(7):573–585. DOI: 10.1002/pi.6632.
[35] Arpitha GR, Mohit H, Madhu P, Others. Effect of sugarcane bagasse and alumina reinforcements on physical, mechanical, and thermal characteristics of epoxy composites using artificial neural networks and response surface methodology. Biomass Convers. Biorefin. 2024;14:12539–12557. DOI: 10.1007/s13399-023-03886-7.
[36] Wang Y, Others. Effects of thermal properties on insulation breakdown behaviors of epoxy/Al₂ O₃ composite with boron nitride doping. Procedia (IEEE 5th ICD) 2024;1–4. DOI: 10.1109/ICD59037.2024.10613220
[37] Khaleel NA, Salih RM, Musa BH. Effect of nanopowders on the surface and adhesion properties of epoxy and polyester-based polymeric coatings. J. Elastomers Plast. 2025;advance online publication. DOI: 10.1177/00952443251326195.
[38] Yang KR, Dai J-Y, Wang S-P, Others. Bio-based epoxy composites demonstrating high temperature breakdown strength and thermal conductivity for high voltage insulation. Chin. J. Polym. Sci. 2025;43:40–52. DOI: 10.1007/s10118-025-3254-5.
[39] Zhang T, Chao X, Liang J, Wang B, Sun M. Enhanced mechanical properties of epoxy composites reinforced with silane-modified Al2 O3 nanoparticles: An experimental study. J. Compos. Sci. 2025;9(5):252. DOI: 10.3390/jcs9050252.
[40] Awais M, Xia F, Zhang T, Rahman TU, Zhao Y, Chen X, Paramane A. Interplay between curing kinetics and thermal aging dynamics of epoxy hybrid composites under different frequencies. Polym. Compos. 2024;advance online publication. DOI: 10.1002/pc.29847.
[41] Paraskar P, Bari P, Mishra S. Influence of amine functionalized graphene oxide on mechanical and thermal properties of epoxy matrix composites. Iran Polym. J. 2020;29(1):47–55. DOI: 10.1007/s13726-019-00772-w.