دنیای نانو

دنیای نانو

مطالعه خصوصیات، ویژگی های ساختاری و روش های سنتز چارچوب های فلز- آلی

نوع مقاله : مروری

نویسندگان
زهرا شیبانی زاده 1
زهرا خلج 1
کسری بهزاد 1
مونا زمانی پدرام 2
مجید منجمی 3
1 گروه فیزیک، واحد شهر قدس، دانشگاه آزاد اسلامی، تهران، ایران
2 گروه انرژی، دانشکده مهندسی مکانیک، دانشگاه خواجه نصیرالدین طوسی، تهران، ایران
3 گروه مهندسی شیمی، واحد تهران مرکز، دانشگاه آزاد اسلامی، تهران، ایران
چکیده
چارچوب‌های فلزی-آلی (MOFs) به‌عنوان دسته‌ای از مواد هیبریدی شبکه‌ای، از ترکیب پیونددهنده‌های معدنی و آلی با یون‌های فلزی به‌صورت منظم تشکیل شده‌اند. چارچوب های فلزی-آلی متشکل از دو بخش اصلی مراکز فلزی و اتصالات آلی هستند. اتصالات آلی که به عنوان واحدهای سازنده ثانویه آلی شناخته می‌شوند، نقش ستون را در ساختار ایفا می‌کنند، در حالی که مراکز فلزی، به عنوان واحدهای سازنده ثانویه معدنی ، نقش مفصل را بر عهده دارند. . ویژگی‌های ساختاری، فیزیکی، مکانیکی و مورفولوژیکی این مواد به طور مستقیم به خصوصیات هر دو بخش وابسته است. این مواد به‌دلیل داشتن سطح ویژه بالا، قابلیت تنظیم اندازه حفره‌ها و ساختارهای متنوع در زمینه های مختلف علمی و صنعتی بسیار مورد توجه قرار گرفته اند با سنتز شبکه ای میتوان MOF هایی با اجزای مشخص تشکیل داد که این امر منجر به تولید کریستال هایی با تخلخل بالا و پایداری شیمیایی و حرارتی زیاد شود. در این مطالعه مروری اجمالی بر جنبه های ساختاری چارچوب های فلزی-آلی، خصوصیات ،طبقه بندی و نامگذاری آن ها و هم چنین رویکردهای سنتز ارائه می‌کند.
کلیدواژه‌ها
چارچوب فلزی-آلی
نانوساختارها
ساختار شبکه
سنتز
موضوعات

عنوان مقاله English

Study of the properties, structural features and synthesis methods of metal-organic frameworks

نویسندگان English

zahra sheibanizadeh 1
Zahra Khalaj 1
Kasra Behzad 1
Mona Zamani Pedram 2
Majid monajemi 3
1 Physics Department, Shahr-e-qods branch, Islamic azad university
2 K N Toosi university
3 Central Tehran Branch
چکیده English

Metal-organic frameworks (MOFs) are a class of network hybrid materials composed of a combination of inorganic and organic linkers with metal ions in a regular manner. Metal-organic frameworks consist of two main parts: metal centers and organic linkages. Organic linkages, known as secondary organic building blocks, play the role of pillars in the structure, while metal centers, known as secondary inorganic building blocks, play the role of joints. . The structural, physical, mechanical, and morphological properties of these materials are directly dependent on the properties of both parts. These materials have attracted much attention in various scientific and industrial fields due to their high specific surface area, ability to adjust pore size, and diverse structures. With network synthesis, MOFs with specific components can be formed, which leads to the production of crystals with high porosity and high chemical and thermal stability. This study provides a brief overview of the structural aspects of metal-organic frameworks, their properties, classification and nomenclature, as well as synthesis approaches.

کلیدواژه‌ها English

Metal-organic framework
nanostructures
network structure
synthesis

  • Li D, Yadav A, Zhou H, Roy K, Thanasekaran P, Lee C. Advances and Applications of Metal-Organic Frameworks (MOFs) in Emerging Technologies: A Comprehensive Review. Global Challenges. 2024;8(2):2300244.

  • Zhou H-C, Long JR, Yaghi OM. Introduction to metal–organic frameworks. ACS Publications; 2012. p. 673-4.

  • Letchumanan I, Wani AA, Shaari N, Beygisangchin M, Kamarudin SK, Karim NA. Metal–Organic Frameworks as a Catalyst and Catalyst Support in Fuel Cells: From Challenges to Catalytic Application. Chemical Engineering & Technology. 2024;47(11):e202300580.

  • Mirkovic I, Lei L, Ljubic D, Zhu S. Crystal growth of metal–organic framework-5 around cellulose-based fibers having a necklace morphology. ACS omega. 2019;4(1):169-75.

  • Xing X-S, Fu Z-H, Zhang N-N, Yu X-Q, Wang M-S, Guo G-C. High proton conduction in an excellent water-stable gadolinium metal–organic framework. Chemical communications. 2019;55(9):1241-4.

  • Hu C, Xiao J-D, Mao X-D, Song L-L, Yang X-Y, Liu S-J. Toughening mechanisms of epoxy resin using aminated metal-organic framework as additive. Materials Letters. 2019;240:113-6.

  • Yang H, Bright J, Kasani S, Zheng P, Musho T, Chen B, et al. Metal–organic framework coated titanium dioxide nanorod array p–n heterojunction photoanode for solar water-splitting. Nano Research. 2019;12:643-50.

  • Tranchemontagne DJ, Mendoza-Cortés JL, O’keeffe M, Yaghi OM. Secondary building units, nets and bonding in the chemistry of metal–organic frameworks. Chemical Society Reviews. 2009;38(5):1257-83.

  • Zou R, Abdel-Fattah AI, Xu H, Zhao Y, Hickmott DD. Storage and separation applications of nanoporous metal–organic frameworks. CrystEngComm. 2010;12(5):1337-53.

  • Batten SR, Champness NR, Chen X-M, Garcia-Martinez J, Kitagawa S, Öhrström L, et al. Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013). Pure and Applied Chemistry. 2013;85(8):1715-24.

  • Batten SR, Neville SM, Turner DR. Coordination polymers: design and application. Royal Society of Chemistry; 2008.

  • Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J. Reticular synthesis and the design of new materials. Nature. 2003;423(6941):705-14.

  • Park KS, Ni Z, Côté AP, Choi JY, Huang R, Uribe-Romo FJ, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proceedings of the National Academy of Sciences. 2006;103(27):10186-91.

  • Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science. 2005;309(5743):2040-2.

  • Tong P, Liang J, Jiang X, Li J. Research progress on metal-organic framework composites in chemical sensors. Critical Reviews in Analytical Chemistry. 2020;50(4):376-92.

  • Ning H, Lu L. Isoreticular Metal-Organic Framework-3 (IRMOF-3): From Experimental Preparation, Functionalized Modification to Practical Applications. Polymers. 2024;16(15):2134.

  • Sarkar S, Grønbech TBE, Mamakhel A, Bondesgaard M, Sugimoto K, Nishibori E, et al. X-ray Electron Density Study of the Chemical Bonding Origin of Glass Formation in Metal–Organic Frameworks. Angewandte Chemie International Edition. 2022;61(22):e202202742.

  • Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, et al. High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science. 2008;319(5865):939-43.

  • Li B, Wen H-M, Zhou W, Chen B. Porous metal–organic frameworks for gas storage and separation: what, how, and why? The journal of physical chemistry letters. 2014;5(20):3468-79.

  • Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. Journal of the American Chemical Society. 2008;130(42):13850-1.

  • Murray LJ, Dincă M, Long JR. Hydrogen storage in metal–organic frameworks. Chemical Society Reviews. 2009;38(5):1294-314.

  • Getachew N, Chebude Y, Diaz I, Sanchez-Sanchez M. Room temperature synthesis of metal organic framework MOF-2. Journal of Porous Materials. 2014;21:769-73.

  • Chen B, Wang X, Zhang Q, Xi X, Cai J, Qi H, et al. Synthesis and characterization of metal-organic frameworks. Chemical Society Reviews. 2009;38(5):1257-83.

  • Zhu X, Li B, Yang J, Li Y, Zhao W, Shi J, et al. Effective adsorption and enhanced removal of organophosphorus pesticides from aqueous solution by Zr-based MOFs of UiO-67. ACS applied materials & interfaces. 2015;7(1):223-31.

  • Surblé S, Serre C, Mellot-Draznieks C, Millange F, Férey G. A new isoreticular class of metal-organic frameworks with the MIL-88 topology. Chemical communications. 2006(3):284-6.

  • Kandelous YM, Nikpassand M, Fekri LZ. Recent Focuses in the Syntheses and Applications of Magnetic Metal-Organic Frameworks. Topics in Current Chemistry. 2024;382(4):30.

  • Khan PN, Pahan S, Sengupta A, Dasgupta K, Vincent T. Post-Synthetically Modified Metal Organic Framework Functionalized with a 1,2-Dihydroxybenzene Chelating Unit for Efficient Removal of Thorium and Uranium.

  • Zhao D, Timmons DJ, Zhou D, Zhou H-C. Tuning the topology and functionality of metal-organic frameworks by ligand design. Accounts of Chemical Research. 2011;44(2):123-33.

  • Horcajada P, Gref R, Baati T, Allan PK, Maurin G, Couvreur P, et al. Metal-organic frameworks in biomedicine. Chemical Reviews. 2012;112(2):1232-68.

  • Saad A, Gobeaux F, Bon V, Plana-Ruiz S, Sicard C, Frégnaux M, et al. Tailoring the dynamics of DUT-5 nanocrystals: from rigid nanoparticles to flexible nanowires. 2024.

  • Yang S, Sun J, Ramirez-Cuesta AJ, Callear SK, David WI, Anderson DP, et al. Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host. Nature chemistry. 2012;4(11):887-94.

  • Ahnfeldt T, Guillou N, Gunzelmann D, Margiolaki I, Loiseau T, Férey G, et al. [Al4(OH)2(OCH3)4(H2N-bdc)3]·xH2O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick. Angewandte Chemie International Edition. 2009;48(28):5163-6.

  • Nadar SS, Vaidya L, Maurya S, Rathod VK. Polysaccharide based metal organic frameworks (polysaccharide-MOF): a review. Coordination Chemistry Reviews. 2019;396:1-21.

  • Greathouse JA, Kinnibrugh TL, Allendorf MD. Adsorption and separation of noble gases by IRMOF-1: grand canonical Monte Carlo simulations. Industrial & Engineering Chemistry Research. 2009;48(7):3425-31.

  • Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, et al. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science. 2002;295(5554):469-72.

  • Pan Y, Liu Y, Zeng G, Zhao L, Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick. Angewandte Chemie International Edition. 2009;48(28):5163-6.

  • Nadar SS, Vaidya L, Maurya S, Rathod VK. Polysaccharide based metal organic frameworks (polysaccharide-MOF): a review. Coordination Chemistry Reviews. 2019;396:1-21.

  • Greathouse JA, Kinnibrugh TL, Allendorf MD. Adsorption and separation of noble gases by IRMOF-1: grand canonical Monte Carlo simulations. Industrial & Engineering Chemistry Research. 2009;48(7):3425-31.

  • Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, et al. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science. 2002;295(5554):469-72.

  • Pan Y, Liu Y, Zeng G, Zhao L, Lai Z. Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system. Chemical Communications. 2011;47(7):2071-3.

  • Ramirez JR, Yang H, Kane CM, Ley AN, Holman KT. Reproducible synthesis and high porosity of mer-Zn(Im)2 (ZIF-10): exploitation of an apparent double-eight ring template. Journal of the American Chemical Society. 2016;138(37):12017-20.

  • Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, et al. Carbon dioxide capture in metal–organic frameworks. Chemical reviews. 2012;112(2):724-81.

  • Wang C-C, Ying JY. Sol–gel synthesis and hydrothermal processing of anatase and rutile titania nanocrystals. Chemistry of materials. 1999;11(11):3113-20.

  • Shi X, Zhu-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework. Chemistry of Materials. 2009;21(8):1410-2.

  • Tranchemontagne DJ, Hunt JR, Yaghi OM. Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0. Tetrahedron. 2008;64(36):8553-7.

  • Lee Y-R, Kim J, Ahn W-S. Synthesis of metal-organic frameworks: A mini review. Korean Journal of Chemical Engineering. 2013;30:1667-80.

  • Rehman A, Farrukh S, Hussain A, Pervaiz E. Synthesis and effect of metal-organic frameworks on CO2 adsorption capacity at various pressures: a contemplating review. Energy & environment. 2020;31(3):367-88.

  • Stock N, Biswas S. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chemical reviews. 2012;112(2):933-69.

  • Mueller U, Schubert M, Teich F, Puetter H, Schierle-Arndt K, Pastre J. Metal–organic frameworks—prospective industrial applications. Journal of Materials Chemistry. 2006;16(7):626-36.

  • Wu Y, Kobayashi A, Halder GJ, Peterson VK, Chapman KW, Lock N, et al. Negative Thermal Expansion in the Metal-Organic Framework Material Cu3(1,3,5-benzenetricarboxylate)2. Angewandte Chemie International Edition. 2008;47(46):8929-32.

  • Mueller U, Puetter H, Hesse M, Wessel H, Guzmann M, Huff J, et al. Method for electrochemical production of a crystalline porous metal organic skeleton material. Google Patents; 2012.

  • Schlesinger M, Schulze S, Hietschold M, Mehring M. Evaluation of synthetic methods for microporous metal-organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3] and [Cu2(btc)(OH)(H2O)]. Microporous and Mesoporous Materials. 2010;132(1-2):121-7.

  • Boldyrev V, Tkáčová K. Mechanochemistry of solids: past, present, and prospects. Journal of materials synthesis and processing. 2000;8:121-32.

  • Pichon A, Lazuen-Garay A, James SL. Solvent-free synthesis of a microporous metal-organic framework. CrystEngComm. 2006;8(3):211-4.

  • Suslick KS, Choe S-B, Cichowlas AA, Grinstaff MW. Sonochemical synthesis of amorphous iron. Nature. 1991;353(6343):414-6.

  • Bang JH, Suslick KS. Applications of ultrasound to the synthesis of nanostructured materials. Advanced materials. 2010;22(10):1039-59.

  • Luche J-L. Synthetic organic sonochemistry. Springer Science & Business Media; 2013.

  • Sono T, Mingos D, Baghurst D, Lickiss P. Novel energy source for reactions. The new chemistry. In: Hall N (editor). Cambridge: Syndicate of the University of Cambridge. 2004.

  • Qiu L-G, Li Z-Q, Wu Y, Wang W, Xu T, Jiang X. Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines. Chemical communications. 2008(31):3642-4.

  • Li Z-Q, Qiu L-G, Xu T, Wu Y, Wang W, Wu Z-Y, et al. Ultrasonic synthesis of the microporous metal-organic Materials Cu3(BTC)2 at ambient temperature and pressure: an efficient and environmentally friendly method. Materials Letters. 2009;63(1):78-80.

  • Zacher D, Yusenko K, Bétard A, Henke S, Molon M, Ladnorg T, et al. Liquid-phase epitaxy of multicomponent layer-based porous coordination polymer thin films of [M(L)(P)0.5] type: importance of deposition sequence on the oriented growth. Chemistry–A European Journal. 2011;17(5):1448-55.

  • Bai M, Zhang JB, Cao LH, Li YP, Wang DZ. Zinc (II) and cadmium (II) metal complexes with bis(tetrazole) ligands: synthesis and crystal structures. Journal of the Chinese Chemical Society. 2011;18(1):69-74.

  • Shekhah O. Layer-by-layer method for the synthesis and growth of surface mounted metal-organic frameworks (SURMOFs). Materials. 2010;3(2):1302-15.

  • Abazari R, Mahjoub AR, Shariati J. Synthesis of a nanostructured pillar MOF with high adsorption capacity towards antibiotics pollutants from aqueous solution. Journal of hazardous materials. 2019;366:439-51.

  • Bakhtiari N, Azizian S. Nanoporous carbon derived from MOF-5: a superadsorbent for copper ions. ACS omega. 2018;3(12):16954-9.

  • Moradi E, Rahimi R, Safarifard V. Sonochemically synthesized microporous metal-organic framework representing unique selectivity for detection of Fe3+ ions. Polyhedron. 2019;159:251-8.

  • Wang X, Chen W, Zhang L, Yao T, Liu W, Lin Y, et al. Uncoordinated amine groups of metal–organic frameworks to anchor single Ru sites as chemoselective catalysts toward the hydrogenation of quinoline. Journal of the American Chemical Society. 2017;139(28):9419-22.

  • Kalaj M, Cohen SM. Postsynthetic modification: an enabling technology for the advancement of metal–organic frameworks. ACS Central Science. 2020;6(7):1046-57.

  • Mandal S, Natarajan S, Mani P, Pankajakshan A. Post-synthetic modification of metal–organic frameworks toward applications. Advanced Functional Materials. 2021;31(4):2006291.

  • Kou W-T, Yang C-X, Yan X-P. Post-synthetic modification of metal–organic frameworks for chiral gas chromatography. Journal of Materials Chemistry A. 2018;6(37):17861-6.

  • Bumstead AM, Pakamore I, Richards KD, Thorne MF, Boyadjieva SS, Castillo-Blas C, et al. Post-synthetic modification of a metal–organic framework glass. Chemistry of Materials. 2022;34(5):2187-96.

  • Zhu C, Peng Y, Yang W. Modification strategies for metal-organic frameworks targeting at membrane-based gas separations. Green Chemical Engineering. 2021;2(1):17-26.

  • Koryakina IG, Bachinin SV, Gerasimova EN, Timofeeva MV, Shipilovskikh SA, Bukatin AS, et al. Microfluidic synthesis of metal–organic framework crystals with surface defects for enhanced molecular loading. Chemical Engineering Journal. 2023;452:139450.

  • Echaide-Górriz C, Clément C, Cacho-Bailo F, Téllez C, Coronas J. New strategies based on microfluidics for the synthesis of metal–organic frameworks and their membranes. Journal of Materials Chemistry A. 2018;6(14):5485-506.

  • Mao C, Wang S, Li J, Feng Z, Zhang T, Wang R, et al. Metal–organic frameworks in microfluidics enable fast encapsulation/extraction of DNA for automated and integrated data storage. ACS nano. 2023;17(3):2840-50.

  • Soni S, Bajpai PK, Arora C. A review on metal-organic framework: Synthesis, properties and application. Nanomaterials. 2020;3(2):87-106.

دنیای نانو
دوره 21، شماره 78
بهار 1404
صفحه 124-107

  • تاریخ دریافت 05 اسفند 1403
  • تاریخ بازنگری 23 مرداد 1404
  • تاریخ پذیرش 29 فروردین 1404