دنیای نانو

دنیای نانو

بررسی تاثیر استفاده از افزودنی‌های مختلف میکرو و نانو کربنی در باتری سرب اسید

نوع مقاله : مروری

نویسندگان
سازمان جهاد دانشگاهی تهران
چکیده
باتری سرب اسیدی (LAB) به دلیل تکنولوژی بالغ، مواد اولیه فراوان و در دسترس، هزینه کم، ایمنی بالا و راندمان بالای بازیافت، سال‌ها مورد استفاده گسترده قرار گرفته است. با این حال، سولفاته شدن برگشت ناپذیر آن به یکی از مسائل کلیدی برای توسعه و کاربرد بیشتر آن تبدیل شده است. باتری سرب اسید با افزودن انواع مختلف مواد کربنی در الکترود منفی در حال پیشرفت و گسترش است و به طور موثری می‌تواند از مشکل سولفاته شدن برگشت ناپذیر الکترود منفی باتری سرب اسید معمول جلوگیری کند. مواد کربنی مختلف به دلایل ساخت شبکه رسانا، تشکیل ساختار متخلخل و اثر فضایی می‌توانند از بزرگ شدن کریستال‌های سولفات سرب جلوگیری به عمل آورند. از این رو، تحقیقات در مورد مواد انواع افزودنی‌های کربنی طی دو دهه اخیر به شدت مورد توجه قرار گرفته است. در این مقاله تلاش شده است که بررسی تاثیر استفاده از افزودنی‌های مختلف میکرو و نانو کربنی (کربن بلک، نانولوله‌های کربنی مختلف، نانو صفحات گرافن، کربن اکتیو، افزودنی پوسته برنج و افزودنی هیبرید کربنی) در الکترود منفی بر تست‌های الکتروشیمیایی عملکردی باتری را به صورت خلاصه نشان دهد.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Investigating the effect of using various micro and nano carbon additives in lead-acid batteries

نویسندگان English

zahra kachoei
mohammadhadi ghasemi
elaheh bohloulbandi
ACECR- Tehran organization, Iran
چکیده English

Lead-acid battery (LAB) has been widely used for many years due to its mature technology, abundant and available raw materials, low cost, high safety and high recycling efficiency. However, its irreversible sulfation has become one of the key issues for its further development and application. The lead-acid battery is developing and expanding by adding various types of carbon materials in the negative electrode, and it can effectively avoid the problem of irreversible sulfation of the negative electrode of the common lead-acid battery. Different carbon materials can prevent the enlargement of lead sulfate crystals due to the construction of conductive network, formation of porous structure and spatial effect. Therefore, research on the materials of various types of carbon additives has been strongly considered during the last two decades.
In this article, an attempt has been made to show the effect of different micro and nano carbon additives (carbon black, different carbon nanotubes, graphene nanoplates, active carbon, rice husk additive and carbon hybrid additive) in the negative electrode on the battery performance electrochemical tests.

کلیدواژه‌ها English

Lead acid battery
carbon nanotubes
graphene nano sheets
carbon black
electrochemical test
[1] Moseley P.T., Garche J., Parker C.D., Rand D.A.J., Valve-Regulated Lead-Acid Batteries, 1st ed.; Elsevier Science: Amsterdam, The Netherlands, 2004; ISBN 978080474731.
[2] Scrosati B., Garche J., Lithium Batteries Status, Prospects and Future, Journal of Power Sources, 2010, 195, 2419–2430.
[3] Pavlov D., Lead-Acid Batteries: Science and Technology, 2nd ed.; Elsevier Science: Amsterdam, The Netherlands, 2017; ISBN 9780444595607.
[4] Liu C., Advanced materials for energy storage, Advanced Materials, 2010, 22(8), E28–62.
[5] David L.; Thomas B.R., Handbook of Batteries, 3rd ed.; McGraw-Hill: New York, ISBN 0-07-135978-8.
[6] Prengaman R.D., Lead acid battery, Encyclopedia of Electrochemical Power Sources, 2009, 655–661.
[7] Saravanan M., Ganesan M., Ambalavanan S., An in-situ Generated Carbon as Negative Electrode Additive for Lead-Acid Batteries, Journal of The Electrochemical Society, 2015.
[8] May G.J., Davidson A., Monahov B., Lead batteries for utility energy storage: A review, Journal of Energy Storage, 2018, 15, 145–157.
[9] Ruetschi P., Review on the lead-acid battery science and technology, Journal of Power Sources, 1977, 2, 3–120.
[10] Soria M.L., Trinidad F., Lacadena J.M., et al., Advanced valve regulated lead-acid batteries for hybrid electric vehicles, Journal of Power Sources, 2007, 168, 12–21.
[11] Technology Strategy Assessment: Findings from Storage Innovations 2030, Lead Batteries Report, U.S. Department of Energy, 2023.
[12] Linnenkoper K., World battery market worth US$ 60 billion. Recycling International, September 30, 2015.
[13] Battery Market Report 2024 (Global Edition), Cognitive Market Research.
[14] Lead Battery Market Data, Battery Council International & Consortium for Battery Innovation.
[15] Reasbeck P., Smith J.G., Batteries for Electric Vehicles, Research Studies Press: Taunton, UK, 1997.
[16] Wagner R., Failure modes of valve-regulated lead/acid batteries in different applications, Journal of Power Sources, 1995, 53(1), 153–162.
[17] Pavlov D., Lead-acid Batteries: Science and Technology. Elsevier: Amsterdam, The Netherlands, 2011.
[18] Pavlov D., Premature Capacity Loss (PCL) of the Positive Lead/Acid Battery Plate: A New Concept to Describe the Phenomenon, Journal of Power Sources, 1993, 42, 345–363.
[19] Ball R.J., Kurian R., Evans R., Stevens R., Failure mechanisms in valve regulated lead/acid batteries for cyclic applications, Journal of Power Sources, 2002, 109(1), 189–202.
[20] Yang J., Hu C., Wang H., Yang K., Liu J.B., Yan H., Review on the research of failure modes and mechanism for lead-acid batteries, International Journal of Energy Research, 2017, 41, 336–52.
[21] Calábek M., Micka K8, 12–21.
[11] Technology Strategy Assessment: Findings from Storage Innovations 2030, Lead Batteries Report, U.S. Department of Energy, 2023.
[12] Linnenkoper K., World battery market worth US$ 60 billion. Recycling International, September 30, 2015.
[13] Battery Market Report 2024 (Global Edition), Cognitive Market Research.
[14] Lead Battery Market Data, Battery Council International & Consortium for Battery Innovation.
[15] Reasbeck P., Smith J.G., Batteries for Electric Vehicles, Research Studies Press: Taunton, UK, 1997.
[16] Wagner R., Failure modes of valve-regulated lead/acid batteries in different applications, Journal of Power Sources, 1995, 53(1), 153–162.
[17] Pavlov D., Lead-acid Batteries: Science and Technology. Elsevier: Amsterdam, The Netherlands, 2011.
[18] Pavlov D., Premature Capacity Loss (PCL) of the Positive Lead/Acid Battery Plate: A New Concept to Describe the Phenomenon, Journal of Power Sources, 1993, 42, 345–363.
[19] Ball R.J., Kurian R., Evans R., Stevens R., Failure mechanisms in valve regulated lead/acid batteries for cyclic applications, Journal of Power Sources, 2002, 109(1), 189–202.
[20] Yang J., Hu C., Wang H., Yang K., Liu J.B., Yan H., Review on the research of failure modes and mechanism for lead-acid batteries, International Journal of Energy Research, 2017, 41, 336–52.
[21] Calábek M., Micka K9, 113–120.
[28] Pavlov D., Nikolov P., Lead-carbon electrode with inhibitor of sulfation for lead-acid batteries operating in the HRPSoC duty, Journal of the Electrochemical Society, 2012, 159, A1215–A1225.
[29] Soria M.L., Hernández J.C., Valenciano J., et al., New developments on valve-regulated lead-acid batteries for advanced automotive electrical systems, Journal of Power Sources, 2005, 144, 473–485.
[30] Chang Y., Mao X.X., Zhao Y.F., et al., Lead-acid battery use in the development of renewable energy systems in China, Journal of Power Sources, 2009, 191, 176–183.
[31] Lam L.T., Haigh N.P., Phyland C.G., et al., Failure mode of valve-regulated lead-acid batteries under high-rate partial state-of-charge operation, Journal of Power Sources, 2004, 133, 126–134.
[32] Ebner E., Burow D., Börger A., Wark M., Carbon blacks for the extension of the cycle life in flooded lead acid batteries for micro-hybrid applications, Journal of Power Sources, 2013, 239, 483–489.
[33] Saravanan M., Sennu P., Ganesan M., Ambalavanan S., Multi-walled carbon nanotubes percolation network enhanced the performance of negative electrode for lead-acid battery, Journal of the Electrochemical Society, 2013, 160(1), A70–A76.
[34] Banerjee A., Ziv B., Shilina Y., Levi E., Luski S., Aurbach D., Single-Wall Carbon Nanotubes Doping in Lead-Acid Batteries: A New Horizon, ACS Applied Materials & Interfaces, 2017, 4, 3634–3643.
[35] Thangarasu S., Palanisamy G., Roh S.H., Jung H.Y., Nanoconfinement and interfacial effect of Pb nanoparticles into nanoporous carbon as a longer life span negative electrode material for hybrid lead-carbon battery, ACS Sustainable Chemistry & Engineering, 2020, 8, 8868–8879.
[36] Pavlov D., Rogachev T., Nikolov P., Petkova G., Mechanism of action of electrochemically active carbons on the processes that take place at the negative plates of lead-acid batteries, Journal of Power Sources, 2009, 191(1), 58–75.
[37] Hong B., Jiang L., Xue H., Liu F., Jia M., Li J., Liu Y., Characterization of nano-lead-doped active carbon and its application in lead-acid battery, Journal of Power Sources, 2014, 270, 332–341.
[38] Enos D.G., Ferreira S.R., Barkholtz H.M., Baca W., Fenstermacher S., Understanding function and performance of carbon additives in lead-acid batteries, Journal of The Electrochemical Society, 2017, 164, A3276–A3284.
[39] کچوئی زهرا، قاسمی محمدهادی، بهلول‌بندی الهه، زمانی سمیرا، «بررسی تاثیر افزودن کربن بلک و کربن اکتیو در آند باتری سرب اسید بر عملکرد الکتروشیمیایی آن»، هفتمین کنفرانس بین‌المللی پژوهش‌های کاربردی در علوم و مهندسی، خرداد ۱۴۰۲.
[40] Long Q., Ma G., Xu Q., Ma C., Nan J., Li A., Chen H., Improving the cycle life of lead-acid batteries using three dimensional reduced graphene oxide under the high-rate partial state-of-charge condition, Journal of Power Sources, 2017, 343, 188–196.
[41] Pröbstle H., Schmitt C., Fricke J., Button cell supercapacitors with monolithic carbon aerogels, Journal of Power Sources, 2002, 105, 189–194.
[42] Li X., Zhang Y., Su Z., Zhao Y., Zhao X., Wang R., Graphene nanosheets as backbones to build a 3D conductive network for negative active materials of lead–acid battery, Journal of Applied Electrochemistry, 2017, 47(5), 619–630.
[43] Yeung K.K., Zhang X., Kwok S.C., Ciucci F., Yuen M.M., Enhanced cycle life of lead-acid battery using graphene as a sulfation suppression additive in negative active material, RSC Advances, 2015, 5(87), 71314–71321.
[44] Naresh V., Bhattacharjee U., Martha S.K., Boron doped graphene nanosheets as negative electrode additive for high performance lead-acid batteries and ultracapacitors, Journal of Alloys and Compounds, 2019, 797, 595–605.
[45] Abdollahzadeh S., Heidari H., Kachoei Z., Lari M.A., Synthesis and application of PbCO3/rGO nanocomposite for enhanced performance in lead-acid batteries, 23rd Iranian Inorganic Chemistry Conference, 2024.
[46] Lin Z.Q., Zhang W.L., Lin N., et al., Long-life lead-acid battery for high-rate partial-state-of-charge operation enabled by a rice-husk-based activated carbon negative electrode additive, ChemistrySelect, 2020, 5, 2551–2558.
[47] Wang L., Zhang H., Zhang W., Cao G., Zhao H., Yang Y., Enhancing cycle performance of lead-carbon battery anodes by lead-doped porous carbon composite and graphite additives, Materials Letters, 2017, 206, 113–116.
[48] کچوئی زهرا، قاسمی محمدهادی، بهلول‌بندی الهه، «استفاده از پلی اتیلن گلیکول به عنوان بایندر مواد فعال صفحه منفی باتری سرب اسید»، هفتمین کنفرانس شیمی کاربردی ایران، شهریور ۱۴۰۳.
[49] بهلول‌بندی الهه، زمانی سمیرا، قاسمی محمدهادی، کچوئی زهرا، «استفاده از نانوسیلیس سنتز شده در باتری سرب-اسید به منظور بهبود خواص الکتروشیمیایی باتری»، هفتمین کنفرانس بین‌المللی پژوهش‌های کاربردی در علوم و مهندسی، خرداد ۱۴۰۲.
دوره 20، شماره 77
زمستان 1403
صفحه 113-100

  • تاریخ دریافت 16 آذر 1403
  • تاریخ بازنگری 10 دی 1403
  • تاریخ پذیرش 21 بهمن 1403