Study of the effect of graphene oxide nanoplatelets on the thermal degradation kinetics of epoxy nanocomposites

Document Type : Original Article

Authors
1 1.Department of Polymer Engineering, Faculty of Engineering, South Tehran Branch, Islamic Azad University, P.O. Box: 19585-466, Tehran, Iran. 2.Nano Research Center, Islamic Azad University, South Tehran Branch.
2 Department of Polymer Engineering, Islamic Azad University, South Tehran Branch, P.O. Box 17776-13651, Tehran, Iran University, Tehran, Iran
Abstract
Epoxy resin is one of the most important thermoset polymers due to its resistance to thermal stress and degradation, which is widely used in coatings and polymer composites. By studying the degradation kinetics of epoxy resins and epoxy nanocomposites, the temperature range and long life of the system are determined. Degradation kinetics modeling is tool for engineers to predict the thermal durability of materials before use in industry, which leads to reduced costs and quality of the designed product. The four most important factors in the study of thermal stability of epoxy nanocomposites in the presence of graphene oxide nanoplatelets are dispersion, weight percentage, type of sample preparation and aspect ratio. In this study, the effect of graphene oxide nanoplatelets and modified graphene oxide nanoplatelets on morphology, mechanical properties, thermal stability and degradation kinetics of epoxy resin has been reported.In this study, the effect of graphene oxide nanoplatelets and modified graphene oxide nanoplatelets on morphology, mechanical properties, thermal stability and degradation kinetics of epoxy resin has been reported.
Keywords

[1] S.P. Vinodhini , J.R. Xavier , Journal of Materials Science, 56,7094-110,(2021).
[2] M.Li, Q.Hu, H.Shan, W.Yu, Z.X.Xu, Chemosphere, 263,128250,(2021).
   [3] A.G.Olabi , M.A.Abdelkareem , T.Wilberforce , E.T.Sayed, Renewable and Sustainable Energy Reviews,135,110026,(2021).
[4] B.Hu, Y.Cong, Y.hua, B.Zhang, B.yan, L.Zhang,Y. Shen, H.Huang, H.zhou, Journal of Materials Science, 55,3712-3727,(2019).
[5] V.R.G. Martínez ,M.Gude .S. Calvo, M.R.M. Miranda ,A. Ureña , Materials Today Communications, 24,100990,(2020).
[6] Y.Xie, C.Liu,W. Liu, L.Liang, S.Wang, F.Zhang, H.Shi, M.Yang, Physicochemical and Engineering Aspects,593,124627,(2020).
[7]F.L. Jin, X.Li ,S.J. Park , Journal of Industrial and EngineeringChemistry ,29, 1-11,( 2015).
[8] A.Xue, B.Zhang ,M. Sun, X.Zhang, J.Li ,L.Wang ,C.Song, International Journal of Adhesion and Adhesives, 88, 11-18,(2019).
[9] S.Chhetri, A.N.C.Chandra,P. Samanta, N.C.Murmu ,T.Kuila, Polymer Testing, 63,1-11,( 2017).
[10] D.Reso,C.N. Cascaval,F. Mustata , C.Ciobanu, Thermochimic.Acta, 383, 119-127, (2002).
[11]  S.Montserrat, J.Málek, Thermochimica. Acta, 228, 47-60,(1993).
 [12]  J. Málek ,Thermochimica .Acta,138, 337-346,(1989).
 [13]  J. Málek, Thermochimica. Acta, 200, 257-269,(1992).
 [14] D.R.Rena , X.Xiong, X.Maa ,S.Liu, J.Wang ,P. Chen ,Y. Zeng , Thermochimica .Acta ,623,15-21,(2016).
[15] L. Li, X .Liao, X .Sheng, P. Liu, Z. Hao, L .He, G .Qin, In Polymers for Advanced  Technology,31, 1865-1874,(2020).
[16] A.Wazalwar,M. Raichur, Thermochimca .Acta, 697, 178857(,2021).
[17]. M. H. Karami ,M. R. Kalaee ,R. Khajavi, O. Moradi, D.Zaarei., Thermal Stability and Thermal Degradation of Epoxy Nanocomposite in The Presence of Full Vulcanized Elastomeric Nano particles, , Advanced materials& Novel Coatings,10,2758-2770,(2021).
 [18] X .Wang, J. Jin, M .Song, Y .Lin, Material Research  Express,3 , 105303,(2016).
[19] M.Nonahal , M.R.Saeb, S.H. Jafari, H.Rastin,H.A. Khonakdar, F.Najafi,F. Simon, Polymer Composite, 39, 2016-2027,(2018).
[20] S.H.Ryu, J.H.Sin, A.M.Shanmugharaj, European Polymer Journal, 52 ,88-97,(2014).
[21] M.Jouyandeh  , E.Yarahmadi, K.Didehban,S. Ghiyasi,M.R. Paran,D. Puglia, J.A.Ali, A.Jannesari, M.R.Saeb, Z. Ranjbar,M.R. Ganjali, Progress in Organic Coatings, 136, 105217,(2019).
 
[22] L.Li,Z. Zeng,J.H. Zou,M. Liang, Thermochimica .Acta, 614, 76-84,(2015).
[23] J.Tian,C. Yang, J.Yang, S.Shi, S.Hao, T, High Performance Polymer,7, 5472-5482 ,(2021).
[24] L.Li, Z.Zeng,H. Zou,M.M. Liang , Thermochimica. Acta, 614, 76-84,(2015).
[25] M.R.Saeb, H.Rastin,M. Shabanian, M.Ghaffari, G.H.Bahlakeh, Progress in Organic Coatings,110 , 172-181,( 2017).
[26] O.Zabihi , A.Hooshafza, F.Moztarzadeh, P.Payravand, A.Afshar, R.Alizadeh , Thermochimica .Acta,527,190-198 , (2012 ).
[27] M.Jouyandeh, N.Rahmati, E.Movahedifard ,B.SH. Hadavand ,Z. Karami ,M. Ghaffari ,  M.Taheri ,E. Bakhshandeh ,H.Vahabi ,M.R. Ganjali ,K. Formela ,M.R. Saeb , Progress in Organic Coatings, 133, 220-228 ,(2019).
[28] M.R.Saeb, M.Nonahal, H.Rastin, M.Shabanian ,M. Ghaffari ,GH. Bahlakeh, S.Ghiyasi,  H.A.Khonakdar , V.Goodarzi , P.Vijayan ,D. Puglia , Progress in Organic Coatings ,112, 176-186,(2017).
[29] O.Zabihi  , M.Aghaie, H.Aghaie ,K. Zare ,Y. Saghapour, Journal of Thermal Analysis and Calorimetry, 117, 53-61 , (2014).
[30] M. Jouyandeh, M.R.Ganjali, A.Jagar, M.Aghazadeh, F.J.Stadler , M.R. Saeb , Progress in Organic Coatings, 136 , 105199 ,(2019).
 
[31] M. H. Karami ,M. R. Kalaee, S.Mazinani,V.G. Martínez, R.M.R.Wellen, G.Hodaifa, A.M.Shanmugharaj, ,K.Kim, Isoconversional Model Approach and Cure Kinetics of Epoxy/ NBR Nanocomposites, Proceeding of the 14th International Seminar on Polymer Science and Technology (ISPST 2020), Tarbiat Modares University, 9-12 November, 9-10, (2020).
[32] M. H. Karami ,M. R. Kalaee, Curing of Epoxy/UFNBRP Nano Composites Using Calorimetric Method, Proceeding of the 11th International Chemical Engineering Congress & Exhibition (IChEC 2020), Tehran University, 15-17 April,15-17, (2020).
 
 
[33] M. H. Karami ,M. R. Kalaee,S. Mazinani, Chemorheology Of Nano Acrylonitrile Butadiene Rubber (n-NBR)/Epoxy Nanocomposites, Proceeding of the 1st International Conference on Rheology (ICOR), Iran Polymer and Petrochemical Institute, 17-18 December ,104-105,(2019).
 
[34] M. H. Karami ,M. R. Kalaee, Modeling of Curing Kinetics of Epoxy Nanocomposites by Time Sweep Method, Proceeding of the National Conference on Advanced Technologies in Energy, Water and Environment, Sharif Energy Research Institute, 3March, 234-241, (2019).
[35] M. H. Karami ,M. R. Kalaee, Chemorheology of Epoxy Nanocomposites in The Presence of Elastomeric Nanoparticles, Proceeding of the National Conference on Advanced Technologies in Energy, Water and Environment, Sharif Energy Research Institute, 3March, 209-216, (2019)
[36] M. H. Karami ,M. R. Kalaee, A Review of the Applications of Cross-linked Elastomeric Nanoparticles., (Persian), Iran Rubber Mag, 25, 37-56, (2021).
 
[37] M. H. Karami ,M. R. Kalaee., A review of the curing kinetics of epoxy nanocomposites/nano clay (Persian), Iran Polymer Technology, Research and Development,6,29-38, (2021).
[38] M. H. Karami ,M. R. Kalaee., Review of degradation kinetics of epoxy nanocomposites in the presence of clay nanoparticles, (Persian), Polymerization, (2021) ,DOI: 10.22063/BASPARESH.2021.2895.1552.
 
[39] M. H. Karami ,M. R. Kalaee, Review of curing kinetics of epoxy nanocomposites in the presence of iron oxide nanoparticles, (Persian), Polymerization, (2021), Doi:10.22063/BASPARESH.2021.2824.1537.
 
[40] M. H. Karami ,M. R. Kalaee, Investigation of the effect of carbon nanotubes on modeling of curing kinetics of epoxy resin., (Persian), Journal of science and engineering elites,6,162-175,(2021).
 
[41] M. H. Karami ,M. R. Kalaee ,R. Khajavi, O. Moradi, D.Zaarei, Effect of vulcanized elastomeric nanoparticles on thermal stability and the maximum decomposition temperatures of epoxy resin,Proceeding of the 17th National Chemical Engineering Congress & Exhibition (IChEC 2021), FerdowsiUniversity of Mashhad, 9-11November , (2021).
[42] M. H. Karami ,M. R. Kalaee ,R. Khajavi, O. Moradi, D.Zaarei , Viscosity modeling of epoxy nanocomposites / elastomeric nanoparticles , Proceeding of the 17th National Chemical Engineering Congress & Exhibition (IChEC 2021), FerdowsiUniversity of Mashhad, 9-11November , (2021).
[43] M.Nonahal, H.Rastin, M.R.Saeb,  M.G.Sari,M.H. Moghadam, P.Zarrintaj , B.Ramezanzadeh, Progress in Organic Coatings, 114 , 233-243,(2018).

  • Receive Date 19 November 2021
  • Revise Date 15 December 2021
  • Accept Date 24 December 2021